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Colloidal hard-sphere crystal growth frustrated by large spherical impurities.

机译:胶体硬球晶体的生长受到较大的球形杂质的阻碍。

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摘要

Impurities affect the nucleation, growth, and structure of crystals. Here we report the effect of large, spherical, polymethylmethacrylate impurities on the crystal growth of monodisperse, hard, polymethylmethacrylate colloids in a density- and optically matching apolar solvent mixture. Crystal growth, initiated at the bottom of the sample, was studied by imaging sequences of two-dimensional xy slices in the plane of the impurity's center with a laser scanning confocal microscope. Impurities form the center of grain boundaries, and a single fluid particle layer around the impurity persists in all cases. The growth rate sensitively depends on the impurity's size. Crystal growth is inhibited to a greater extent near smaller impurities, pointing to local crystal frustration induced by the curvature of the impurity.
机译:杂质会影响晶体的成核,生长和结构。在这里,我们报告了大的球形聚甲基丙烯酸甲酯杂质对密度和光学匹配的非极性溶剂混合物中单分散的硬聚甲基丙烯酸甲酯胶体晶体生长的影响。通过使用激光扫描共聚焦显微镜在杂质中心平面中二维xy切片的成像序列研究了样品底部开始的晶体生长。杂质形成晶界的中心,并且在所有情况下,围绕杂质的单个流体颗粒层都会持续存在。生长速率敏感地取决于杂质的尺寸。较小的杂质附近会更大程度地抑制晶体生长,这表明由杂质的曲率引起的局部晶体受挫。

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